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Fault code description - three-way catalytic converter effect too low - AD07.61-P-4000-16A

1 Fault code P0422 right
P0432 left
2 Fault storage after expiry of test duration and fault
Actuation of the engine diagnosis indicator lamp (EURO3/4)
or CHECK ENGINE (MIL) malfunction indicator lamp USA ONLY
after two successive driving cycles with faults
3 Checking frequency continuous
4 Checked signal or status Voltage ratio (amplitudes) of oxygen sensor signal downstream of TWC to oxygen sensor signal upstream of TWC
5 Fault setting conditions 
Limit value Checking duration
The amplitude of the O2 sensor signal downstream of TWC may not exceed a maximum of 75% of the amplitude of the O2 sensor signal upstream of TWC ca. 170 s
6 Check prerequisites
  • Engine speed 1000 to 2700 rpm
  • Load approx. 22 % to 52 %
  • Catalyst temperature > 380 °C
  • Lambda control enabled and Lambda > 0.4
  • No fault in O2 sensor heater or aging
  • Air pressure more than approx. 780 hPa (i.e. no test is performed above a height of approx. 2500 m)
7 INSPECT
After a repair, carry out tests and driving instructions
The tests 1 to 4 must be carried out together one after the other without switching off the engine.
1st Check O 2  sensor heater 
Vehicle is stationary and in drive position P
Coolant temperature > 80 °C
Let engine run at 2000 up to 2500 rpm for approx. 2 minutes
Then let engine run in idle for approx. 6 minutes
2nd Check aging of O2 sensor upstream TWC [KAT] 
Drive vehicle in drive mode D for approx. 3 minutes at approx. 70 km/h on a straight road
3rd Check catalytic converter effect 
Drive vehicle in drive mode D for approx. 3 minutes at approx. 80 up to 90 km/h on a straight road
4th Check self-adaptation of mixture formation. 
Vehicle is stationary and in drive position P
Let engine run in idle for approx. 3 minutes
If the individual test is performed, this is displayed in the HHT as follows: If the test is passed without a fault, "-V-" is placed in dark (repair is successful). If the test is passed with a fault, "-F-" is placed in dark. After ignition OFF the tests are again restored (white field). Only after the test has been performed once again, the corresponding fields are once again placed in dark. Carry out a new test only after approx. 10 seconds ignition OFF.
8 IMPORTANT The three way catalytic converter is evaluated on the basis of its ability to store oxygen. Several measurements must be performed in the specified engine speed and load range. The results are compared with a map and a fault is detected in this way.
The amplitude of the O2 sensor voltage downstream TWC must be less than the amplitude of the O2 sensor voltage upstream TWC (Note: If e.g. no monolith was built into the catalytic converter, the O2 sensor signals upstream TWC and downstream TWC would be identical).
If the fault codes for the three-way catalytic converter and for the oxygen sensor upstream of TWC are output simultaneously, first replace the oxygen sensor upstream of TWC.
If then a TWC fault is no longer detected, and if the effect of the three-way catalytic converter has been slightly reduced, it does not need to be replaced yet.

Illustrated on engine 112 EURO3/4 

Fig 1: Identifying Three Way Catalytic Converter Components
G04606028Courtesy of MERCEDES-BENZ USA