Circuit/System Verification
WARNING: This page is about a different car, the 2009 GMC Sierra, 2009 GMC Cab & Chassis Sierra, 2009 Chevrolet Silverado, and 2009 Chevrolet Cab & Chassis Silverado. However, it is still accessible from the selected car via links, so may be relevant.
Command the Rear Defog Request ON and OFF with the scan tool. The rear window defogger should turn ON and OFF when changing between the commanded states.