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Three-Way Catalyst (TWC) Conversion Efficiency

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A TWC requires a stoichiometric fuel ratio, 14.7 pounds of air to 1 pound of fuel (14.7:1), for high conversion efficiency. In order to achieve these high efficiencies, the air/fuel ratio must be tightly controlled with a narrow window of stoichiometry. Deviations outside of this window greatly decrease the conversion efficiency. For example a rich mixture decreases the HC and CO conversion efficiency while a lean mixture decreases the NO x conversion efficiency.

Fig 1: TWC Conversion Efficiency Chart
G04587093Courtesy of FORD MOTOR CO.