Catalytic Converter
Catalyst Conversion
The catalyst within the converter promotes a chemical reaction, which oxidizes the hydrocarbons and the carbon monoxide that are present in the exhaust gas. This process converts the hydrocarbons and the carbon monoxide into water vapor and carbon dioxide, and reduces the nitrogen oxide, converting the nitrogen oxide into nitrogen.
Oxygen Storage
The catalyst stores oxygen. The engine control module (ECM) monitors this process by using heated oxygen sensors that are in the exhaust stream before and after the catalyst. The heated oxygen sensors produces an output signal that the ECM uses to calculate the oxygen storage capacity of the catalyst. This indicates the ability of the catalyst to convert the exhaust emissions efficiently. The ECM monitors the efficiency of the catalyst by monitoring the heated oxygen sensors during an off-idle, deceleration fuel cut-off event. When the catalyst is functioning properly, the post catalyst heated oxygen sensors response to the fuel conditions during the deceleration fuel cut-off event is slow compared to the response of the pre catalyst heated oxygen sensors. When the post heated oxygen sensors response is near that of the pre heated oxygen sensors, the oxygen storage capability and efficiency of the catalyst may be degraded below an acceptable threshold.
Cold Start Strategy
The catalyst must be warmed to efficiently reduce the emissions. The cold start strategy is to reduce the amount of time it takes to warm the catalyst. During a cold start, the engine spark timing and fuel injection are altered to allow the catalyst to warm quickly. The ECM monitors the following to build an exhaust energy model:
- Engine airflow
- Engine coolant temperature
- Engine idle speed
- Engine run time
- Fuel Injection
- Spark advance
The actual model is then compared to the expected exhaust energy model.
Fuel Trim Bias
Fuel trim bias is used to keep the post catalyst air/fuel ratio within a predetermined range. This allows optimal catalyst efficiency under various operating conditions. The ECM constantly monitors how lean or rich the fuel trim bias is commanded, to determine if the fuel trim bias is greater than a calibrated amount.